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- W2004694592 abstract "A series of underivatized dipeptides containing proline as either the N- or C-terminal amino acid, and a series of underivatized peptides containing two to six glycines have been studied. The complexity and position of the second amino acid, the mode of ionization and the detectability of characteristic fragments were examined. All the dipeptide spectra exhibited two fragment ions that are characteristic of their molecular weight but characteristic fragments that would permit the determination of their structure were not always observed. Molecular weight information in the (Gly)n spectra was only present up to the tripeptide. When the number of amino acids was larger, only a small and uncharacteristic fragment ion (highly stabilized) was observed. It is concluded that, under presently available conditions, the unequivocal determination of the primary structure of a mixture of underivatized small peptides is not possible by direct liquid introduction liquid chromatography—mass spectrometry." @default.
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- W2004694592 date "1985-01-01" @default.
- W2004694592 modified "2023-10-14" @default.
- W2004694592 title "Direct liquid introduction mass spectrometry of some underivatized depeptides and polypeptides" @default.
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- W2004694592 doi "https://doi.org/10.1016/s0021-9673(01)93545-9" @default.
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