Matches in SemOpenAlex for { <https://semopenalex.org/work/W2004758312> ?p ?o ?g. }
- W2004758312 endingPage "457" @default.
- W2004758312 startingPage "450" @default.
- W2004758312 abstract "The purpose of the present work was to investigate a liquid chromatographic method for the measurement of relative hydrogen bond basicities of dilute species. This type of determination cannot be done with conventional reversed-phase liquid chromatography due to the silanophilic interactions of basic solutes with the silica packing material. The studies were done on a polymeric stationary phase with pendant phenol groups that act as powerful hydrogen bond donors. Solute retention was evaluated in terms of two hydrogen bond basicity scales, beta 2H and beta 2C, and a steric hindrance parameter, Es. beta 2H and beta 2C are basicity scales based on the free energy of forming 1:1 hydrogen bond complexes and the retention on a strong hydrogen bond donor gas chromatographic phase, respectively. The Es parameter characterizes the steric effect experienced by the solute acceptor site. It is shown that retention correlates very strongly with beta 2H and less strongly with beta 2C. The log k' values need only two descriptive parameters, i.e., beta 2H and Es, to give a good fit. As a whole, retention on the phenolic polymeric phase provides an efficient method for the measurement of relative hydrogen bond basicities." @default.
- W2004758312 created "2016-06-24" @default.
- W2004758312 creator A5002152167 @default.
- W2004758312 creator A5067345680 @default.
- W2004758312 creator A5082263870 @default.
- W2004758312 creator A5087650939 @default.
- W2004758312 date "1994-02-15" @default.
- W2004758312 modified "2023-10-13" @default.
- W2004758312 title "Liquid chromatographic study of solute hydrogen bond basicity" @default.
- W2004758312 cites W1905957412 @default.
- W2004758312 cites W1964247399 @default.
- W2004758312 cites W1970887795 @default.
- W2004758312 cites W1977825428 @default.
- W2004758312 cites W1978525775 @default.
- W2004758312 cites W1981104346 @default.
- W2004758312 cites W1984971224 @default.
- W2004758312 cites W1985383130 @default.
- W2004758312 cites W1987323764 @default.
- W2004758312 cites W1987369037 @default.
- W2004758312 cites W1993501962 @default.
- W2004758312 cites W1996985082 @default.
- W2004758312 cites W2008031838 @default.
- W2004758312 cites W2015232762 @default.
- W2004758312 cites W2015771022 @default.
- W2004758312 cites W2015911412 @default.
- W2004758312 cites W2017818104 @default.
- W2004758312 cites W2018477281 @default.
- W2004758312 cites W2018690424 @default.
- W2004758312 cites W2020298029 @default.
- W2004758312 cites W2026876513 @default.
- W2004758312 cites W2028339944 @default.
- W2004758312 cites W2030932350 @default.
- W2004758312 cites W2044015631 @default.
- W2004758312 cites W2045578603 @default.
- W2004758312 cites W2049717384 @default.
- W2004758312 cites W2054082457 @default.
- W2004758312 cites W2055914734 @default.
- W2004758312 cites W2057003691 @default.
- W2004758312 cites W2059103780 @default.
- W2004758312 cites W2062680784 @default.
- W2004758312 cites W2066450193 @default.
- W2004758312 cites W2067914942 @default.
- W2004758312 cites W2070009817 @default.
- W2004758312 cites W2074545853 @default.
- W2004758312 cites W2082947065 @default.
- W2004758312 cites W2084275543 @default.
- W2004758312 cites W2085436898 @default.
- W2004758312 cites W2087383256 @default.
- W2004758312 cites W2089049959 @default.
- W2004758312 cites W2093688811 @default.
- W2004758312 cites W2093938060 @default.
- W2004758312 cites W2112347196 @default.
- W2004758312 cites W2127627293 @default.
- W2004758312 cites W2147143434 @default.
- W2004758312 cites W2163925201 @default.
- W2004758312 cites W1568237197 @default.
- W2004758312 doi "https://doi.org/10.1021/ac00076a006" @default.
- W2004758312 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/8154582" @default.
- W2004758312 hasPublicationYear "1994" @default.
- W2004758312 type Work @default.
- W2004758312 sameAs 2004758312 @default.
- W2004758312 citedByCount "21" @default.
- W2004758312 countsByYear W20047583122017 @default.
- W2004758312 countsByYear W20047583122018 @default.
- W2004758312 crossrefType "journal-article" @default.
- W2004758312 hasAuthorship W2004758312A5002152167 @default.
- W2004758312 hasAuthorship W2004758312A5067345680 @default.
- W2004758312 hasAuthorship W2004758312A5082263870 @default.
- W2004758312 hasAuthorship W2004758312A5087650939 @default.
- W2004758312 hasConcept C112887158 @default.
- W2004758312 hasConcept C121332964 @default.
- W2004758312 hasConcept C122032599 @default.
- W2004758312 hasConcept C178790620 @default.
- W2004758312 hasConcept C185592680 @default.
- W2004758312 hasConcept C201194858 @default.
- W2004758312 hasConcept C26873012 @default.
- W2004758312 hasConcept C2779892579 @default.
- W2004758312 hasConcept C32909587 @default.
- W2004758312 hasConcept C43617362 @default.
- W2004758312 hasConcept C44280652 @default.
- W2004758312 hasConcept C512968161 @default.
- W2004758312 hasConceptScore W2004758312C112887158 @default.
- W2004758312 hasConceptScore W2004758312C121332964 @default.
- W2004758312 hasConceptScore W2004758312C122032599 @default.
- W2004758312 hasConceptScore W2004758312C178790620 @default.
- W2004758312 hasConceptScore W2004758312C185592680 @default.
- W2004758312 hasConceptScore W2004758312C201194858 @default.
- W2004758312 hasConceptScore W2004758312C26873012 @default.
- W2004758312 hasConceptScore W2004758312C2779892579 @default.
- W2004758312 hasConceptScore W2004758312C32909587 @default.
- W2004758312 hasConceptScore W2004758312C43617362 @default.
- W2004758312 hasConceptScore W2004758312C44280652 @default.
- W2004758312 hasConceptScore W2004758312C512968161 @default.
- W2004758312 hasIssue "4" @default.
- W2004758312 hasLocation W20047583121 @default.
- W2004758312 hasLocation W20047583122 @default.
- W2004758312 hasOpenAccess W2004758312 @default.
- W2004758312 hasPrimaryLocation W20047583121 @default.