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• W2004786711 endingPage "5390" @default.
• W2004786711 startingPage "5382" @default.
• W2004786711 abstract "The competitive degradation of six carbamate insecticides by membrane anodic Fenton treatment (AFT), a new Fenton treatment technology, was carried out in this study. The carbamates studied were dioxacarb, carbaryl, fenobucarb, promecarb, bendiocarb, and carbofuran. The results indicate that AFT can effectively degrade these insecticides in both single component and multicomponent systems. The carbamates compete for hydroxyl radicals, and their kinetics obey the previously developed AFT kinetic model quite well. Hydroxyl radical reaction rate constants were obtained, and they decrease in the following order: dioxacarb approximately carbaryl > fenobucarb > promecarb > bendiocarb > carbofuran. The AFT is shown to have higher treatment efficiency at higher temperature. Degradation products of the carbamates were determined by gas chromatography/mass spectrometry, and it appears that degradation can be initiated by hydroxyl radical attack at different sites in the molecule, depending on the individual structure of the compound. Substituted phenols are the commonly seen degradation products. The AFT treatment can efficiently remove the chemical oxygen demand of the carbamate mixture, significantly increasing the biodegradability. Earthworm studies show that the AFT is also an effective detoxification process." @default.
• W2004786711 created "2016-06-24" @default.
• W2004786711 creator A5060453788 @default.
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• W2004786711 date "2003-08-01" @default.
• W2004786711 modified "2023-09-26" @default.
• W2004786711 title "Competitive Degradation and Detoxification of Carbamate Insecticides by Membrane Anodic Fenton Treatment" @default.
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• W2004786711 doi "https://doi.org/10.1021/jf034311f" @default.
• W2004786711 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/12926887" @default.
• W2004786711 hasPublicationYear "2003" @default.
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