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- W2004791184 abstract "The selective binding of alkali metal and quaternary ammonium ions to anionic surfactant films at the air/solution interface has been investigated using the ion flotation technique. Surfactant anions studied were the dodecyl phosphate monoanion, the hexadecyl phosphate dianion, bis(2-ethylhexyl) phosphate, dodecanoate, and dodecyl sulfate. Alkali metal ions display only weak selectivity at adsorbed films of all surfactants studied. The binding strength increases in the order Na+ < K+ < Rb+ < Cs+, with the exception of films of dodecanoate, for which the ions have equal affinity, and the hexadecyl phosphate dianion, for which the selectivity sequence is Cs+ < Rb+ < K+ < Na+. By contrast, the binding of quaternary ammonium counterions to adsorbed films of anionic surfactants has a striking dependence on the surfactant headgroup. Results are interpreted using a model which includes solvation of the headgroups and competing counterions and is compared with competitive binding of phosphate, sulfate, and acetat..." @default.
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- W2004791184 date "1999-11-17" @default.
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- W2004791184 title "Cation Selectivity at Air/Anionic Surfactant Solution Interfaces" @default.
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- W2004791184 doi "https://doi.org/10.1021/la990695l" @default.
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