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• W2004802302 startingPage "618" @default.
• W2004802302 abstract "We present a quantitative low-energy electron diffraction (LEED) surface-crystallographic study of the complete adsorption geometry of glycine adsorbed on Cu{110} in the ordered p(3 × 2) phase. The glycine molecules form bonds to the surface through the N atoms of the amino group and the two O atoms of the deprotonated carboxylate group, each with separate Cu atoms such that every Cu atom in the first layer is involved in a bond. Laterally, N atoms are nearest to the atop site (displacement, 0.41 Å). The O atoms are asymmetrically displaced from the atop site by 0.54 and 1.18 Å with two very different O–Cu bond lengths of 1.93 and 2.18 Å. The atom positions of the upper-most Cu layers show small relaxations within 0.07 Å of the bulk-truncated surface geometry. The unit cell of the adsorbate layer consists of two glycine molecules, which are related by a glide-line symmetry operation. This study clearly shows that a significant coverage of adsorbate structures without this glide-line symmetry must be rejected, on the grounds of both the energy dependence of the spot intensities (LEED-IV curves) and systematic absences in the LEED pattern." @default.
• W2004802302 created "2016-06-24" @default.
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• W2004802302 date "2011-12-12" @default.
• W2004802302 modified "2023-10-17" @default.
• W2004802302 title "Complete Experimental Structure Determination of the p(3 × 2)<i>pg</i> Phase of Glycine on Cu{110}" @default.
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• W2004802302 doi "https://doi.org/10.1021/jp2057282" @default.
• W2004802302 hasPublicationYear "2011" @default.
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