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- W2004804310 endingPage "1907" @default.
- W2004804310 startingPage "1907" @default.
- W2004804310 abstract "A series of polycyano–polycadmate host clathrates including a methylviologen dication (MV2+), which is a strong electron acceptor, and an organic molecule, such as alcohols, haloalkanes, ethers and small aromatics, and two complexes built of a polycyano–polycadmate and MV2+ have been synthesized. Single crystal X-ray diffraction experiments on ten clathrates and the two complexes revealed their 3-D network polycyano–polycadmate structures constructed with Cd2+ ions and CN− bridges. The network structures are classified into five structure types. Type I, II and III were found in the clathrates, and Type IV and V were found in the two complexes. Type I and II have cage-like cavities and each of the cavities includes one guest, MV2+ or an organic molecule. Type III has a channel-like cavity where MV2+ ions and organic molecules are included. Type IV and V have 3-Dcavities, the shape of which is neither cage-like nor channel-like, for embracing MV2+. Although all compounds were colorless and the formation of a charge transfer complex between MV2+ and a neutral guest in the clathrates was not confirmed from the crystal structure data and diffuse reflectance spectra, some of them showed a color change from colorless to blue on UV irradiation, which arose from the reduction of MV2+ to a methylviologen radical cation MV+˙." @default.
- W2004804310 created "2016-06-24" @default.
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- W2004804310 date "2002-01-01" @default.
- W2004804310 modified "2023-10-03" @default.
- W2004804310 title "Polycyano–polycadmate host clathrates including a methylviologen dication. Syntheses, crystal structures and photo-induced reduction of methylviologen dication" @default.
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