FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2004805889> ?p ?o ?g. }

• W2004805889 endingPage "4934" @default.
• W2004805889 startingPage "4927" @default.
• W2004805889 abstract "Abstract Approaches toward the synthesis of thio‐β‐ D ‐galactose derivatives are described. These compounds were prepared from the parent carbohydrates: D ‐galactose, methyl β‐ D ‐galactoside and methyl β‐ D ‐glucoside, respectively. It was found that not only the strategies of protecting group introduction and selective deprotection, but also the choices of solvent and nucleophilic reagent concentration were crucial to allow the efficient introduction of sulfur at different positions of the galactose ring. The effects from the solvent, the nucleophilic reagent concentration, and the protecting group patterns have been investigated. The results clearly show that ester protecting groups play highly important roles for the synthesis of thio‐containing carbohydrates, requiring nonpolar solvents to suppress the neighboring group participation. For the Lattrell–Dax (nitrite‐mediated) inversion reaction, employed in the synthetic route to the 2‐thio‐β‐ D ‐galactoside, intramolecular nucleophilic attack, as well as strongerstereospecific ester activation, are necessary to overcome hindrance from 4,6‐ O ‐benzylidene protection.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)" @default.
• W2004805889 created "2016-06-24" @default.
• W2004805889 creator A5049977264 @default.
• W2004805889 creator A5055143950 @default.
• W2004805889 creator A5058182950 @default.
• W2004805889 creator A5072488525 @default.
• W2004805889 date "2007-09-20" @default.
• W2004805889 modified "2023-10-03" @default.
• W2004805889 title "Synthesis of Positional Thiol Analogs of β-D-Galactopyranose" @default.
• W2004805889 cites W169053664 @default.
• W2004805889 cites W1971330949 @default.
• W2004805889 cites W1975630826 @default.
• W2004805889 cites W1978573262 @default.
• W2004805889 cites W1984270679 @default.
• W2004805889 cites W1991921325 @default.
• W2004805889 cites W1998164180 @default.
• W2004805889 cites W2001647891 @default.
• W2004805889 cites W2008379633 @default.
• W2004805889 cites W2009508880 @default.
• W2004805889 cites W2014529628 @default.
• W2004805889 cites W2022907852 @default.
• W2004805889 cites W2027937744 @default.
• W2004805889 cites W2032240280 @default.
• W2004805889 cites W2044135175 @default.
• W2004805889 cites W2050281395 @default.
• W2004805889 cites W2052191192 @default.
• W2004805889 cites W2058400330 @default.
• W2004805889 cites W2059288783 @default.
• W2004805889 cites W2060355268 @default.
• W2004805889 cites W2076094176 @default.
• W2004805889 cites W2088724065 @default.
• W2004805889 cites W2101097761 @default.
• W2004805889 cites W2129232972 @default.
• W2004805889 cites W2131474026 @default.
• W2004805889 cites W2133323763 @default.
• W2004805889 cites W2133516442 @default.
• W2004805889 cites W2133538505 @default.
• W2004805889 cites W2166149847 @default.
• W2004805889 cites W2175229795 @default.
• W2004805889 cites W2949517483 @default.
• W2004805889 cites W2951816307 @default.
• W2004805889 cites W4211178909 @default.
• W2004805889 cites W4251775387 @default.
• W2004805889 doi "https://doi.org/10.1002/ejoc.200700364" @default.
• W2004805889 hasPublicationYear "2007" @default.
• W2004805889 type Work @default.
• W2004805889 sameAs 2004805889 @default.
• W2004805889 citedByCount "34" @default.
• W2004805889 countsByYear W20048058892012 @default.
• W2004805889 countsByYear W20048058892013 @default.
• W2004805889 countsByYear W20048058892014 @default.
• W2004805889 countsByYear W20048058892015 @default.
• W2004805889 countsByYear W20048058892016 @default.
• W2004805889 countsByYear W20048058892017 @default.
• W2004805889 countsByYear W20048058892018 @default.
• W2004805889 countsByYear W20048058892019 @default.
• W2004805889 countsByYear W20048058892020 @default.
• W2004805889 countsByYear W20048058892021 @default.
• W2004805889 countsByYear W20048058892022 @default.
• W2004805889 crossrefType "journal-article" @default.
• W2004805889 hasAuthorship W2004805889A5049977264 @default.
• W2004805889 hasAuthorship W2004805889A5055143950 @default.
• W2004805889 hasAuthorship W2004805889A5058182950 @default.
• W2004805889 hasAuthorship W2004805889A5072488525 @default.
• W2004805889 hasConcept C155647269 @default.
• W2004805889 hasConcept C160964918 @default.
• W2004805889 hasConcept C161790260 @default.
• W2004805889 hasConcept C178790620 @default.
• W2004805889 hasConcept C178907741 @default.
• W2004805889 hasConcept C181199279 @default.
• W2004805889 hasConcept C185592680 @default.
• W2004805889 hasConcept C21951064 @default.
• W2004805889 hasConcept C2776392439 @default.
• W2004805889 hasConcept C2778173381 @default.
• W2004805889 hasConcept C2779746882 @default.
• W2004805889 hasConcept C2780263894 @default.
• W2004805889 hasConcept C2780471494 @default.
• W2004805889 hasConcept C2781253882 @default.
• W2004805889 hasConcept C2781324293 @default.
• W2004805889 hasConcept C40875361 @default.
• W2004805889 hasConcept C71240020 @default.
• W2004805889 hasConcept C75079739 @default.
• W2004805889 hasConceptScore W2004805889C155647269 @default.
• W2004805889 hasConceptScore W2004805889C160964918 @default.
• W2004805889 hasConceptScore W2004805889C161790260 @default.
• W2004805889 hasConceptScore W2004805889C178790620 @default.
• W2004805889 hasConceptScore W2004805889C178907741 @default.
• W2004805889 hasConceptScore W2004805889C181199279 @default.
• W2004805889 hasConceptScore W2004805889C185592680 @default.
• W2004805889 hasConceptScore W2004805889C21951064 @default.
• W2004805889 hasConceptScore W2004805889C2776392439 @default.
• W2004805889 hasConceptScore W2004805889C2778173381 @default.
• W2004805889 hasConceptScore W2004805889C2779746882 @default.
• W2004805889 hasConceptScore W2004805889C2780263894 @default.
• W2004805889 hasConceptScore W2004805889C2780471494 @default.
• W2004805889 hasConceptScore W2004805889C2781253882 @default.
• W2004805889 hasConceptScore W2004805889C2781324293 @default.
• W2004805889 hasConceptScore W2004805889C40875361 @default.

• next