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- W2004832161 abstract "In an attempt to improve our understanding of the basic mechanisms of the degradation of aromatic pollutants, the photocatalysed reactions of five selected organic systems, namely 2-naphthoic acid (1), 2,6-dichloro-4-nitro aniline (2, dichloran), 4-nitro phenyl acetate (3) 1,3-dially-2-thio-urea (4), and 7-hydroxy-4-methyl coumarin (5) has been investigated in water or acetonitrile/water mixture in the presence of titanium dioxide and oxygen. An attempt has been made to identify the products formed during the photooxidation process through GC/MS analysis technique. The photolysis of 2-naphthoic acid (1) showed the formation of 2-formylcinnamaldehyde (11) and 1,2-benzenedicarboxaldehyde (13) whereas 2,6-dichloro-4-nitro aniline (2) gave rise to 2,6-dichloro-4-nitro phenol (14). However, the photolysis of 4-nitro phenyl acetate (3) yielded 4-nitrphenol (15). The illumination of 1,3-diallyl-2-thio-urea (4), on the other hand, led to the formation of 1,3-diallyl urea (19). Product 2,4-dihydroxy acetophenone (25) was identified in case of 7-hydroxy-4-methyl coumarin (5). The products have been identified by comparing the molecular ion and mass fragmentation peaks of the products with those reported in the GC–MS library. A probable mechanism for the formation of the products has been proposed." @default.
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- W2004832161 date "2005-06-01" @default.
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- W2004832161 title "Photoinduced electron transfer reaction of few selected organic systems in presence of titanium dioxide" @default.
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- W2004832161 doi "https://doi.org/10.1016/j.molcata.2005.02.025" @default.
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