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- W2004853801 abstract "Direct catalytic diarylation with (hetero)arylhalides of arenes containing an heterocycle (pyridine, oxazoline, pyrazole) has been performed with a ruthenium catalyst assisted by a coordinating base. It constitutes a green process for cross-coupled C–C bond formation without any metal salt waste. The new catalytic system is based on [HRu(codyl)2]BF4/2KY (KY: KOAc, KOPiv, KPI (potassium phtalimide)] in which the assisting ligand Y promotes the initial cleavage of C–H bonds. It is shown that the efficiency of the Ru/2KY system strongly depends on the nature of both substrates." @default.
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- W2004853801 date "2011-01-01" @default.
- W2004853801 modified "2023-10-07" @default.
- W2004853801 title "C–H bond functionalisation with [RuH(codyl)2]BF4 catalyst precursor" @default.
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- W2004853801 doi "https://doi.org/10.1039/c1gc15642j" @default.
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