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- W2004865137 abstract "The complete and unequivocal assignment of the 24 ribose proton signals of m62A(1)-U(2)-m62A(3)-U(4) by means of 500 MHz NMR spectroscopy at 17°C is given. This assignment is based on scrupulous decoupling experiments carried out at various temperatures. Analysis of the observed chemical shifts and coupling constants of the tetramer shows that the two fragments -m62A(3)-U(4) comprising the 3′-end occur mainly in the classical right-handed stack conformation, whereas at the 5′-end the -U(2)- residue appears bulged out in favour of a less well-defined stacking interaction between the bases -m62A(1)- and -m62A(3)-. Conformational populations about each of the torsional degrees of freedom along the backbone are discussed. A modernized version of pseudo-rotation analysis is used to delineate the conformational behaviour of the four ribose rings." @default.
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- W2004865137 date "1981-01-01" @default.
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- W2004865137 title "Conformational analysis of a modified ribotetranucleoside triphosphate: m<sup>6</sup><sub>2</sub>A-U-m<sup>6</sup><sub>2</sub>A-U studied in aqueous solution by nuclear magnetic resonance at 500 MHz<sup>1</sup>" @default.
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- W2004865137 doi "https://doi.org/10.1093/nar/9.6.1405" @default.
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