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• W2004882658 abstract "High-purity Al2O3 compacts were doped with 0–350 ppm (by weight) of MgO using a liquid immersion technique and equilibrated at temperatures between 1700° and 2000°C under hydrogen. The solubility limits of MgO in Al2O3 at temperatures of 1720° and 1880°C were very low, ∼75 and 175 ppm, respectively. Variation of MgO solubility with temperature could be represented by the equation, ln Mg/Al = 3.80–2.63 × 104/T. The small MgO solubilities were understood by the high enthalpy (326 kJ/mol) of solution. The results of this study suggested that previous investigations on sintering and grain-growth mechanisms in MgO-doped Al2O3 were probably not done in single-phase Al2O3 solid solutions. However, the conclusions on sintering and grain-growth mechanisms in prior research work in MgO-doped A2O3 may be correct. The effects of SiO2 impurity and grain size on MgO solubility are discussed. Previous grain-growth experiments in MgO-doped Al2O3 are described that demonstrate the clearest evidence for grain-boundary mobility controlled by a solid-solution mechanism." @default.
• W2004882658 created "2016-06-24" @default.
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• W2004882658 date "2004-12-20" @default.
• W2004882658 modified "2023-10-01" @default.
• W2004882658 title "Solubility of Magnesia in Polycrystalline Alumina at High Temperatures" @default.
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• W2004882658 doi "https://doi.org/10.1111/j.1151-2916.2001.tb00671.x" @default.
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