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• W2004893273 abstract "The kinetics of formation of N-diketohydrindylidenehistidinatocopper(II) complex has been investigated in the presence of cationic cetyltrimethylammonium bromide (CTAB) surfactant in aqueous medium (pH = 5.0). Similarly in aqueous solution, the reaction followed irreversible first-order kinetics with respect to [Ninhydrin]. Although the reaction mechanism remained unaltered by micelles, a typical kψ-[CTAB] profile was observed, that is, with a progressive increase in [CTAB], the reaction rate increased, reached a maximum value, and then decreased. The results are treated quantitatively in terms of the kinetic pseudo-phase model. Activation parameters were also evaluated and a large decrease in ΔS# shows the formation of a well-structured activated complex. It was found that anionic sodium dodecyl sulphate (SDS) and non-ionic Triton X-100 (TX-100) surfactants have no effect on the reaction. © 1999 John Wiley & Sons, Inc. Int J Chem Kinet 31: 729–736, 1999" @default.
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• W2004893273 date "1999-01-01" @default.
• W2004893273 modified "2023-10-18" @default.
• W2004893273 title "Micellar effects on the rates of the condensation reaction between copper(II)-histidine complex and ninhydrin" @default.
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• W2004893273 doi "https://doi.org/10.1002/(sici)1097-4601(1999)31:10<729::aid-jck6>3.0.co;2-g" @default.
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