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• W2004915427 abstract "A novel ligand exchange approach to catalytic asymmetric deprotonation−electrophilic trapping has been developed that uses 1.3 equiv of s-BuLi, 0.06−0.2 equiv of chiral diamine ((−)-sparteine or a (+)-sparteine surrogate), and 1.2 equiv of achiral bispidine. The methodology is illustrated with a range of examples and gives access to either enantiomer of useful chiral products in good yields using substoichiometric amounts of chiral diamines." @default.
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• W2004915427 date "2005-11-03" @default.
• W2004915427 modified "2023-10-15" @default.
• W2004915427 title "Catalytic Asymmetric Deprotonation Using a Ligand Exchange Approach" @default.
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• W2004915427 doi "https://doi.org/10.1021/ja056026d" @default.
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