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• W2004959780 abstract "Abstract Seven new diorganotin (IV) compounds (1–7) of Schiff bases derived from dihalo‐substituted salicylaldehyde and thiosemicarbazide were synthesized. The general formulae for the compounds are {R 2 Sn[OArCHNNC(NH 2 )S]}, where R = Me, n ‐Bu, Ph and Bz, and Ar = ‐C 6 H 2 (3‐Br‐, 5‐Cl) or ‐C 6 H 2 (3,5‐Br 2 ), and these were characterized by UV–vis, IR and NMR ( 1 H, 13 C, 119 Sn) spectroscopy and elemental analysis. Five structures were also investigated by X‐ray crystallography. All molecules are mononuclear, five‐coordinate with a tridentate ligand coordinating the tin atom through the thiolate‐S, phenoxide‐O and imino‐N atoms. The coordination geometries for the n ‐butyl compounds approach square pyramidal arrangements with distortions towards trigonal pyramidal occurring for the di‐methyl and di‐phenyl compounds which display wider CSnC angles. The potential of the new compounds against six fungal pathogens ( Bipolaris sorokiniana, Helminthosporium oryzae, Altreneria brassicae, Alterneria kikuchiana, Stemphylium pori and Colletotrichum capsici ) were investigated for six different crops ( Triticum aestivum, Oryzae sativa, Brassica nigra, Brassica oleracea, Allium cepa and Capcicum annum ) and demonstrated significant activity. None of the investigated compounds displayed adverse phytotoxicity at concentrations as high as 100 ppm. Copyright © 2010 John Wiley & Sons, Ltd." @default.
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• W2004959780 date "2010-11-23" @default.
• W2004959780 modified "2023-10-07" @default.
• W2004959780 title "Crystal structure, anti‐fungal activity and phytotoxicity of diorganotin compounds of dihalo‐substituted [(2‐hydroxyphenyl) methylideneamino]thiourea" @default.
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• W2004959780 doi "https://doi.org/10.1002/aoc.1698" @default.
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