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- W2004994861 abstract "Electron paramagnetic resonance studies are performed on the radiation damage fragments in KH2AsO4-doped KH2PO4. The products include a variety of radicals from the dopant, namely, the radical AsO44- occupying a single site in the unit cell, eight sites of AsO32- of group b and eight sites AsO32- of group c, the only difference between b and c being the 75As hyperfine constants. In addition, a pseudo Vk centre [AsO4 ⃛ PO4]5- is also obtained in this system. The structure and stereochemistry of these species are well accounted for by the crystal point group symmetries. The g-values and 75As coupling constants all follow expectations from simple hybridisation and MO description. Untersuchungen der Elektronenparamagnetischen Resonanz werden an den Strahlungsdamage-Produkten von KH2AsO4-dotiertem KH2PO4 durchgeführt. Diese Produkte schließen eine Vielzahl von Radikalen des Dopanten ein; das Radikal AsO44-, das einen isolierten Platz in der Einheitszelle einnimmt, acht Plätze von AsO32- der Gruppe b und acht Plätze AsO32- der Gruppe c. Der einzige Unterschied zwischen b und c besteht in der 75As-Hyperfeinkonstante. Zusätzlich wird noch ein Pseudo-Vk-Zentrum [AsO4 ⃛ PO4]5- in diesem System gefunden. Die Struktur und Stereochemie dieser Proben werden an Hand der Kristall-Punktgruppensymmetrien geklärt. Die g-Werte und die 75As-Kopplungskonstanten folgen Erwartungen aus einfachen Hybridisierungs-und MO-Beschreibungen." @default.
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- W2004994861 date "1977-02-01" @default.
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- W2004994861 title "Electron paramagnetic resonance study of X-irradiated arsenate-Doped Phosphate: KH2AsO4/KH2PO4" @default.
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- W2004994861 doi "https://doi.org/10.1002/pssa.2210390238" @default.
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