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- W2005008051 abstract "Monooxygenation of aromatic compounds by dioxygen in the presence of catalytic amounts of an iron(II) salt and tetrahydropterins as reducing agents occurs with a regioselectivity favouring meta-hydroxylation of arenes bearing an electron-donating substituent, such as anisole, phenetole, toluene, and ethylbenzene. Comparison of similar systems using various reducing agents showed that only tetrahydropterins and ascorbate led to such a major meta-hydroxylation. The tetrahydropterin- and ascorbate-dependent systems should be useful for the preparation of meta-hydroxylated metabolites of aromatic drugs, as shown here in the case of diclofenac." @default.
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- W2005008051 date "2004-04-01" @default.
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- W2005008051 title "Monooxygenation of aromatic compounds by dioxygen with bioinspired systems using non-heme iron catalysts and tetrahydropterins: comparison with other reducing agents and interesting regioselectivity favouring meta-hydroxylation" @default.
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- W2005008051 doi "https://doi.org/10.1016/j.tet.2004.03.006" @default.
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