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- W2005008052 abstract "Abstract The reduction of copper (II) chloride by molybdenum and rhenium biscyclopentadienyl hydrides upon their interaction in donor-type solvents has been studied by NMR, X-ray diffraction, and magnetic methods. It is established that the ionic complex [(η 5 -C 5 H 5 ) 2 Re] + [CuCl 2 ] − forms ortho rhombic crystals with a - 13.696(2) A, b = 7.317(1) A, c = 5.969(1) A, space group Pm 2 1 n , Z = 2. The cyclopentadienyl rings make a bent-sandwich with an angle between the ring centres and Re atom of 150.1°; the ClCuCl angle being 174.8° and the ReCu minimum distance 4.346(29) A. The solution of [(η 5 -C 5 H 5 ) 2 Re] + [CuCl 2 ] − seems to activate the CH bond of the C 5 H 5 rings, which results in the addition of the [(C 5 H 5 )(C 5 H 4 )ReH] + hydride ion." @default.
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- W2005008052 date "1984-01-01" @default.
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- W2005008052 title "Reduction of copper (II) chloride by molybdenum and rhenium biscyclopentadienyl hydrides. Investigation of the crystal and molecular structure of [(η5-C5H5)2Re]+[CuCl2]−" @default.
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- W2005008052 doi "https://doi.org/10.1016/s0277-5387(00)84623-9" @default.
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