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- W2005011331 abstract "Frequency response analysis was used to study the physical adsorption and diffusion of ethene on 13X molecular sieves, a system for which the adsorption isotherm has a relatively large curvature. Transient experiments were carried out in a Berty reactor with effluent sample analysis every 0.5 s. Mathematical models describing sorption−diffusion were solved by applying perturbation theory and Laplace transform. Fast Fourier transform was used to separate the responses into the fundamental and first harmonic frequencies. The slope and curvature of the sorption isotherm and effective diffusivity were determined by applying the Hooke and Jeeves algorithm. The sorption isotherm constructed with data from dynamic experiments was comparable to the isotherm from steady-state experiments." @default.
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- W2005011331 date "1996-01-01" @default.
- W2005011331 modified "2023-09-23" @default.
- W2005011331 title "Nonlinear Sorption Isotherm of Zeolites by Frequency Response Analysis" @default.
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- W2005011331 doi "https://doi.org/10.1021/ie950212i" @default.
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