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- W2005013024 abstract "The order-disorder transition in a lattice hole model of a polydisperse dense system of semiflexible chain macromolecules is studied within the mean-field approximation and by Monte-Carlo methods. The polymer chains consist of ‘stiff’ or ‘flexible’ monomer units which associate at a given density and temperature in the process of reversible equilibrium polymerization. The system goes from an ordered state of parallel infinite rods into a lower density state of differently long disoriented chains at a temperature which is influenced by the chain stiffness and by the ratio between inter- and intrachain interactions. The mechanism of the transition is different from that of Flory and represents rather a polymerization transition." @default.
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- W2005013024 date "1993-01-01" @default.
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- W2005013024 title "Phase transitions in polydisperse polymer melts" @default.
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- W2005013024 doi "https://doi.org/10.1016/0032-3861(93)90090-w" @default.
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