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- W2005015857 abstract "The CS2 carbon atom of the η2-CS3Me ligand in the cobalt(II) and nickel(II) complexes [M(tppme)(S2CSMe)][BPh4][M = Co (1) or Ni (2), tppme = 1,1,1-tris(diphenylphosphinomethyl)ethane] is an electrophilic centre, susceptible to attack by nucleophiles such as PEt3 and H–; as a result the new complexes [M(tppme){S2C(PEt3)SMe}][BPh4][M = Co or Ni] and [Co(tppme){S2C(H)SMe}] are obtained. Reaction of an excess of NaBH4 with (1) gives the complexes [Co(tppme)(S2CS)], [Co(tppme)(η2-CS2)](8), and [Co(tppme)(S2CO)]. The C–SMe bond in both compounds (1) and (2) is cleaved by sodium to give the η2-CS2 complexes (8) and [Ni(tppme)(η2-CS2)] respectively. Replacement of the SMe group in complex (2) by NEt2, followed by reaction of the resultant dithiocarbamate complex with NaBH4, affords the nickel(I) thiolato-complex [Ni(tppme)(SH)], which reacts with CS2 to give the trithiocarbonate complex [Ni(tppme)(S2CS)]. All the products have been fully characterized. Mechanisms for the formation of the reaction products are proposed and discussed." @default.
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- W2005015857 date "1983-01-01" @default.
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- W2005015857 title "Reactivity of η<sup>2</sup>-CS<sub>3</sub>Me metal complexes as electrophiles" @default.
- W2005015857 doi "https://doi.org/10.1039/dt9830002419" @default.
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