Matches in SemOpenAlex for { <https://semopenalex.org/work/W2005015964> ?p ?o ?g. }
- W2005015964 abstract "The generation of cationic palladium complexes that contain halogenated alkyl ligands (RX) and their reactivity with vinyl chloride, ethylene, and CO are described. {(nHex)HC(mim)2}Pd(CHCl2)Cl (1; nHex = n-hexyl, mim = N-methylimidazol-2-yl) reacts with 0.5 equiv of [Li(Et2O)2.8][B(C6F5)4] to form [{{(nHex)HC(mim)2}Pd(CHCl2)}2(μ-Cl)][B(C6F5)4] as a 1:1 mixture of diastereomers (3a,b). 3a,b do not react with vinyl chloride. The reaction of 1 with 1 equiv of [Li(Et2O)2.8][B(C6F5)4] in the presence of ethylene or CO yields [{(nHex)HC(mim)2}Pd(CHCl2)(L)][B(C6F5)4] adducts (L = ethylene (4), CO (5)). The reaction of (dppp)Pd(nC3F7)Me (7; dppp = 1,3-bis(diphenylphosphino)propane) with [HNMePh2][B(C6F5)4] yields [(dppp)Pd(nC3F7)(NMePh2)][B(C6F5)4] (8). 8 does not react with vinyl chloride or ethylene but does react with CO to form [(dppp)Pd(nC3F7)(CO)][B(C6F5)4] (9). 4, 5, and 9 do not undergo insertion under mild conditions. The reaction of (tBu2bipy)Pd(CH2Cl)Cl (10; tBu2bipy = 4,4‘-di-tert-butyl-2,2‘-bipyridin..." @default.
- W2005015964 created "2016-06-24" @default.
- W2005015964 creator A5048852695 @default.
- W2005015964 creator A5058003131 @default.
- W2005015964 creator A5063625158 @default.
- W2005015964 creator A5073146208 @default.
- W2005015964 date "2003-12-31" @default.
- W2005015964 modified "2023-09-24" @default.
- W2005015964 title "Generation and Insertion Reactivity of Cationic Palladium Complexes That Contain Halogenated Alkyl Ligands" @default.
- W2005015964 cites W1583344827 @default.
- W2005015964 cites W1964620959 @default.
- W2005015964 cites W1968760903 @default.
- W2005015964 cites W1979728899 @default.
- W2005015964 cites W1980550341 @default.
- W2005015964 cites W1982900856 @default.
- W2005015964 cites W1984226634 @default.
- W2005015964 cites W1985548136 @default.
- W2005015964 cites W1987089761 @default.
- W2005015964 cites W1991018449 @default.
- W2005015964 cites W1991280887 @default.
- W2005015964 cites W2001749459 @default.
- W2005015964 cites W2001859541 @default.
- W2005015964 cites W2004315945 @default.
- W2005015964 cites W2004461992 @default.
- W2005015964 cites W2005421179 @default.
- W2005015964 cites W2006973236 @default.
- W2005015964 cites W2007240261 @default.
- W2005015964 cites W2007603687 @default.
- W2005015964 cites W2010735001 @default.
- W2005015964 cites W2016271477 @default.
- W2005015964 cites W2017580422 @default.
- W2005015964 cites W2021038963 @default.
- W2005015964 cites W2022334477 @default.
- W2005015964 cites W2032642012 @default.
- W2005015964 cites W2035161221 @default.
- W2005015964 cites W2035807220 @default.
- W2005015964 cites W2037786816 @default.
- W2005015964 cites W2038024075 @default.
- W2005015964 cites W2040351681 @default.
- W2005015964 cites W2040869259 @default.
- W2005015964 cites W2041527154 @default.
- W2005015964 cites W2042395811 @default.
- W2005015964 cites W2046132654 @default.
- W2005015964 cites W2048118471 @default.
- W2005015964 cites W2049543666 @default.
- W2005015964 cites W2055079767 @default.
- W2005015964 cites W2056883035 @default.
- W2005015964 cites W2059022295 @default.
- W2005015964 cites W2061121083 @default.
- W2005015964 cites W2063714603 @default.
- W2005015964 cites W2063820931 @default.
- W2005015964 cites W2063972905 @default.
- W2005015964 cites W2064497313 @default.
- W2005015964 cites W2066797441 @default.
- W2005015964 cites W2068054822 @default.
- W2005015964 cites W2071140820 @default.
- W2005015964 cites W2071875569 @default.
- W2005015964 cites W2073172346 @default.
- W2005015964 cites W2074620934 @default.
- W2005015964 cites W2074756034 @default.
- W2005015964 cites W2086279704 @default.
- W2005015964 cites W2094506189 @default.
- W2005015964 cites W2097659204 @default.
- W2005015964 cites W2169649371 @default.
- W2005015964 cites W2207070880 @default.
- W2005015964 cites W2325983882 @default.
- W2005015964 cites W2329401414 @default.
- W2005015964 cites W2605093829 @default.
- W2005015964 cites W4230014471 @default.
- W2005015964 cites W4235166588 @default.
- W2005015964 cites W95846580 @default.
- W2005015964 doi "https://doi.org/10.1021/om034211z" @default.
- W2005015964 hasPublicationYear "2003" @default.
- W2005015964 type Work @default.
- W2005015964 sameAs 2005015964 @default.
- W2005015964 citedByCount "39" @default.
- W2005015964 countsByYear W20050159642012 @default.
- W2005015964 countsByYear W20050159642013 @default.
- W2005015964 countsByYear W20050159642014 @default.
- W2005015964 countsByYear W20050159642015 @default.
- W2005015964 countsByYear W20050159642016 @default.
- W2005015964 countsByYear W20050159642019 @default.
- W2005015964 countsByYear W20050159642020 @default.
- W2005015964 countsByYear W20050159642021 @default.
- W2005015964 crossrefType "journal-article" @default.
- W2005015964 hasAuthorship W2005015964A5048852695 @default.
- W2005015964 hasAuthorship W2005015964A5058003131 @default.
- W2005015964 hasAuthorship W2005015964A5063625158 @default.
- W2005015964 hasAuthorship W2005015964A5073146208 @default.
- W2005015964 hasConcept C108204754 @default.
- W2005015964 hasConcept C138716334 @default.
- W2005015964 hasConcept C142724271 @default.
- W2005015964 hasConcept C155647269 @default.
- W2005015964 hasConcept C15920480 @default.
- W2005015964 hasConcept C161790260 @default.
- W2005015964 hasConcept C178790620 @default.
- W2005015964 hasConcept C183882617 @default.
- W2005015964 hasConcept C185592680 @default.
- W2005015964 hasConcept C204787440 @default.
- W2005015964 hasConcept C2776345496 @default.