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- W2005016502 abstract "In the reaction of nitrous acid with n-propylamine perchlorate labelled with 14C at the nitrogen-bonded carbon, no rearrangement of the n-propyl cation chain, but isomerization of the type: with simultaneous isomerization of n-propyl cation to isopropyl cation takes place. A similar isomerization has been observed in the reaction of nitrous acid with the perchlorate of cyclohexylamine-114C. This results in the linking of the hydroxyl in a portion of the resultant cyclohexanol molecules to carbon atoms not participating in the C-N bond of the original cyclohexylamine." @default.
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- W2005016502 modified "2023-09-24" @default.
- W2005016502 title "Rearrangement of alkyl-cations formed during reaction between nitrous acid and alkylamine perchlorates" @default.
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- W2005016502 doi "https://doi.org/10.1016/s0040-4020(01)92657-2" @default.
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