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- W2005018725 abstract "Abstract Different photoinitiators based on Barton thiohydroxamic esters, O ‐acyl‐ N ‐hydroxy‐pyridine‐2(1H)‐thione and O ‐acyl‐ N ‐hydroxy‐thiazole‐2(3H)‐thione derivatives, were tested in photopolymerization reactions through time‐resolved FTIR spectroscopy. Good rates of polymerization and final monomer conversion were obtained for some compounds. The excited state processes, investigated by time resolved absorption spectroscopy, lie on a fast singlet state cleavage leading to thiyl and alkyl radicals. Both the pyridine‐2(1H)‐thiyl and alkyl radicals are able to initiate a polymerization, in contrast with the thiazole‐2(3H)‐thiyl radical. A triplet state is observed for some derivatives. Computational studies help to describe the excited state properties and show a strong difference in the spin localization in the formed thiyl initiating radicals. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008" @default.
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- W2005018725 date "2008-04-10" @default.
- W2005018725 modified "2023-10-18" @default.
- W2005018725 title "Investigation of Barton esters as radical photoinitiators" @default.
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- W2005018725 doi "https://doi.org/10.1002/app.26618" @default.
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