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- W2005018911 abstract "The high efficient palladium-catalyzed Suzuki–Miyaura reactions of potassium aryltrifluoroborates 3 with 5-iodo-1,3-dioxin-4-ones 2a–b in water as only solvent in the presence of n-Bu4NOH as base is reported. The respective 5-aryl-1,3-dioxin-4-ones 4a–n were obtained in good to excellent yields. The catalyst system provides high efficiency at low load using electronically diverse coupling partners. The obtained 2,2,6-trimethyl-5-aryl-1,3-dioxin-4-ones were transformed into corresponding α-aryl-β-ketoesters 6 by reaction with an alcohol in the absence of solvent." @default.
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- W2005018911 date "2010-01-01" @default.
- W2005018911 modified "2023-10-17" @default.
- W2005018911 title "Highly efficient palladium-catalyzed Suzuki–Miyaura reactions of potassium aryltrifluoroborates with 5-iodo-1,3-dioxin-4-ones in water: an approach to α-aryl-β-ketoesters" @default.
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- W2005018911 doi "https://doi.org/10.1016/j.tet.2009.11.027" @default.
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