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- W2005019872 abstract "A model to describe the behavior of photoexcited electrodes in an electrochemical cell is developed. In addition to the bulk semiconductor properties, the important parameters are a surface recombination parameter Sr and a surface electron transfer parameter St. It is the electron transfer process across the interface that leads to current in the external circuit. Using experimental curves for oxygen evolution at an n‐type TiO2 electrode and Hall‐Shockley‐Read recombination to determine Sr, it is shown that the I‐V curve in anodic bias is controlled by the competition between Sr and St. The physical basis for St is discussed and experimental approaches to investigate surface reactions are suggested." @default.
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- W2005019872 title "A model for the current‐voltage curve of photoexcited semiconductor electrodes" @default.
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- W2005019872 doi "https://doi.org/10.1063/1.323417" @default.
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