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- W2005029145 abstract "Abstract The equation of state of an open system containing water in an electric field of strength E greater than 10 8 V m −1 leads to a phase diagram with two‐phase and single‐phase regions in the Π,E,T coordinates ( Π =electrostriction pressure). The phases differ by their degree of orientation of H 2 O molecules in the field. The phase transition is discontinuous with respect to E . The calculation shows that the discontinuity vanishes at the critical point: Π c ≈0.2 GPa, E c ≈10 9 V m −1 and ${{rm T}{{{rm E}hfill atop chfill}}}$ below 313 K. The thermal effect of the transition is calculated and compared with an experiment at the Hg/aqueous electrolyte interface found in the literature." @default.
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- W2005029145 date "2005-08-05" @default.
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- W2005029145 title "Phase Diagram of Electrostricted H2O at Surfaces of Electrodes at 273-373 K: Electric Critical Point of Water" @default.
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- W2005029145 doi "https://doi.org/10.1002/cphc.200500106" @default.
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