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- W2005029920 abstract "The first-order rate constants for thermal decomposition of benzyl phenylazo sulfone (BPA, 1) have been determined spectrophotometrically in six solvents using the free radical scavenging technique with a stable Koelsch free radical. Activation parameters in the non-polar solvents such as benzene, toluene, anisole and chlorobenzene were almost the same, but in the two polar solvents, pyridine and nitrobenzene, activation entropies decreased significantly as compared with those in the non-polar solvents. This can be explained by the solvation of the polar solvent in the transition state leading to a phenyldiazenyl and α-toluenesulfonyl radical pair." @default.
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- W2005029920 date "1976-08-01" @default.
- W2005029920 modified "2023-09-28" @default.
- W2005029920 title "Studies of Sulfonyl Radicals. III. Solvent Effects on the Thermal Decomposition of Benzyl Phenylazo Sulfone" @default.
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- W2005029920 doi "https://doi.org/10.1246/bcsj.49.2272" @default.
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