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- W2005032087 abstract "Das monozyklische Phosphoran (EtO)3P[OC(CF3)2C(CF3)2O] 1 hydrolysierte zu einem Gemisch zweier Phosphorsäureester, einem azyklischen 3 und einem zyklischer 4, ohne daß das Trihydroxyphosphoran 2 erhalten werden konnte. Iodtrimethylsilan 6 überführte 1 in das silylierte Derivat von 4, welches neben (Me3SiO)2P(O)OC(CF3)2OSiMe3 8 auch bei der Umsetzung von 3 und 4 mit Me3SiCl/(Me3Si)2NH entstand. Die Reaktion von (Me3SiO)3P 10 mit Hexafluoraceton ergab kein Tris(trimethylsiloxy)-phosphoran 5, sondern den Phosphonsäureester 11, der beim Erhitzen unter Fluortrimethylsilanabspaltung in (Me3SiO)2P(O)OC(CF3) CF2 12 überging. Bis(trimethylsilyl)phosphates of 1,1,1,4,4,4-Hexafluoro-2,3-bis(trifluoromethyl)-2,3-butanediol and 1,1,1,3,3-Pentafluoro-2-propenol The monocyclic phosphorane (EtO)3P[OC(CF3)2C(CF3)2O] 1 was hydrolized to give a mixture of an acyclic and a cyclic phosphate, 3 and 4. The trihydroxyphosphorane 2 could not be obtained. Iodotrimethylsilane 6 converts 1 into the silylated derivative of 4 which was found also besides (Me3SiO)2P(O)OC(CF3)2C(CF3)2OSiMe3 8 in the reaction of 3 and 4 with Me3SiCl/(Me3Si)2NH. (Me3SiO)3P 10 and hexafluoroacetone did not yield the tris(trimethylsiloxy)phosphorane 5, but the phosphonate 11 which gave (Me3SiO)2P(O)OC(CF3) CF2 12 upon heating with the loss of fluorotrimethylsilane." @default.
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- W2005032087 date "1986-02-01" @default.
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- W2005032087 title "Phosphors�urebis(trimethylsilyl)ester des 1,1,1,4,4,4-Hexafluor-2,3-bis(trifluormethyl)-2,3-butandiols und des 1,1,1,3,3-Pentafluor-2-propenols" @default.
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- W2005032087 doi "https://doi.org/10.1002/zaac.19865330203" @default.
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