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• W2005039708 endingPage "3555" @default.
• W2005039708 startingPage "3551" @default.
• W2005039708 abstract "The alkoxycarbonyl complexes [(C5Me5)M(µ-pz)(µ-I)2Rhl(CO2R)(CO)][M = Rh, R = Me, (4), or Et, (5); M = Ir, R = Me, (6); pz = pyrazolate] were prepared by treating the corresponding dicarbonyl complex [(C5Me5)ClM(µ-pz)2Rh(CO)2][M = Rh, (1), or Ir, (3)] with molecular iodine in methanol [(4), (6)] or ethanol [(5)] and in the presence of sodium salts (i.e. NaBPh4, NaI·2H2O). The molecular structure of compound (6) was determined by X-ray diffraction: monoclinic space group C2/c with a= 28.574(3), b= 8.688(1), c= 19.321 (2)Å, β= 96.44(1)°, and Z= 8. The structure was refined to R= 0.037 for 2 789 observed reflections [F 5.0σ(F)] and 236 parameters. The complex is dinuclear with the two metals, bridged by two iodides and a pyrazolate ligand. The rhodium exhibits distorted-octahedral co-ordination involving three terminal ligands: an iodide, a carbonyl, and a methoxycarbonyl group formed during the preparative reaction." @default.
• W2005039708 created "2016-06-24" @default.
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• W2005039708 date "1990-01-01" @default.
• W2005039708 modified "2023-09-25" @default.
• W2005039708 title "Synthesis and characterization of the alkoxycarbonyl complexes [(C₅Me₅)M(µ-pz)(µ-I)₂Rhl(CO₂R)(CO)](M = Rh, R = Me or Et; M = Ir, R = Me; pz = pyrazolate). Molecular structure of [(C₅Me₅)Ir(µ-pz)(µ-I)₂Rhl(CO₂Me)(CO)]" @default.
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• W2005039708 doi "https://doi.org/10.1039/dt9900003551" @default.
• W2005039708 hasPublicationYear "1990" @default.
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