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- W2005052089 abstract "Die Struktur des 3,3,3,3,6,6,6,6-Octamethyl-4,4′-bi(1-thiacycloheptyliden)-5,5′-dions (3) wurde röntgenkristallographisch bestimmt. Die Verbindung kristallisiert in der Raumgruppe Pbca mit den Gitterkonstanten a = 17.59, b = 19.29, c = 12.10 Å. Z = 8. Das 2-Buten-1,4-dionsystem ist stark gespannt. Die beiden Carbonylgruppen stehen nahezu senkrecht auf der verdrillten zentralen Doppelbindung. The Structure of a Highly Strained 2-Butene-1,4-dione The structure of 3,3,3,3,6,6,6,6-octamethyl-4,4′-bi(1-thiacycloheptylidene)-5,5′-dione (3) has been determined by single-crystal X-ray diffraction. The compound crystallizes in the space group Pbca with a = 17.59. b = 19.29. c = 12.10 Å, Z = 8. The 2-butene-1,4-dione moiety is highly distorted. The two carbonyl groups are nearly perpendicular to the twisted central double bond." @default.
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- W2005052089 date "1978-05-01" @default.
- W2005052089 modified "2023-09-25" @default.
- W2005052089 title "Die Struktur eines hochgespannten 2-Buten-1,4-dions" @default.
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- W2005052089 doi "https://doi.org/10.1002/cber.19781110539" @default.
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