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- W2005058154 abstract "Abstract The betain like carbodiphosphorane CO 2 adduct O 2 CC(PPh 3 ) 2 ( 1a ) can serve as a ligand versus hard Lewis acids from main group compounds. Thus, reaction of 1a with InCl 3 , InI 3 and SnCl 2 in polar solvents leads to the addition compounds [Cl 3 In{O 2 CC(PPh 3 ) 2 }] ( 2 ), [Cl 2 SnO 2 CC(PPh 3 ) 2 }] ( 3 ) and the salt like compound [I 2 In{O 2 CC(PPh 3 ) 2 } 2 ]I ( 4 ) in good yields. Whereas in the indium compounds 1a acts as a chelating ligand, in the tin compound the molecule coordinates with one oxygen atom only as a monodentate ligand. 4 has a pyramidal structure with a stereochemical active pair of electrons. All compounds could be characterized by X‐ray analyses and the usual spectroscopic methods." @default.
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- W2005058154 date "2005-07-26" @default.
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- W2005058154 title "The Coordination Chemistry of the Ylide Adduct O2CC(PPh3)2; Preparation, Crystal Structures, and Spectroscopic Properties of [Cl3In{O2CC(PPh3)2}], [Cl2Sn{O2CC(PPh3)2}], and [I2In{O2CC(PPh3)2}2]I" @default.
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- W2005058154 doi "https://doi.org/10.1002/zaac.200500184" @default.
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