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- W2005060498 abstract "A Raney catalyst prepared from an alloy consisting of 43 wt.% copper, 39 wt.% aluminium and 18 wt.% zinc and a commercial copper oxide-zinc oxide-alumina catalyst were tested in methanol synthesis in the temperature range 430–530 K, using a GHSV of 10000 h−1, and constant total pressure of 5000 kPa. Total carbon oxide concentration in the synthesis gas was in the range 15–20 vol.%. It was found that the catalysts had the same activity per unit area of copper and showed almost identical responses to changes in process conditions despite the different morphologies resulting from the methods of catalyst preparation. A Raney copper catalyst, prepared from CuAl2 and containing less than 1% of residual aluminium, was found to be active in methanol synthesis. The results suggest that the same active species are involved in methanol synthesis in both types of catalyst, and that these active species involve copper metal." @default.
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- W2005060498 date "1986-12-01" @default.
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- W2005060498 title "A comparison of Raney copper-zinc and coprecipitated copper-zinc-aluminium oxide methanol syntheses catalysts" @default.
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- W2005060498 doi "https://doi.org/10.1016/s0166-9834(00)82508-7" @default.
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