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• W2005066543 abstract "Abstract The monoammoniate of lithium amidoborane, Li(NH 3 )NH 2 BH 3 , was synthesized by treatment of LiNH 2 BH 3 with ammonia at room temperature. This compound exists in the amorphous state at room temperature, but at −20 °C crystallizes in the orthorhombic space group Pbca with lattice parameters of a =9.711(4), b =8.7027(5), c =7.1999(1) Å, and V =608.51 Å 3 . The thermal decomposition behavior of this compound under argon and under ammonia was investigated. Through a series of experiments we have demonstrated that Li(NH 3 )NH 2 BH 3 is able to absorb/desorb ammonia reversibly at room temperature. In the temperature range of 40–70 °C, this compound showed favorable dehydrogenation characteristics. Specifically, under ammonia this material was able to release 3.0 equiv hydrogen (11.18 wt %) rapidly at 60 °C, which represents a significant advantage over LiNH 2 BH 3 . It has been found that the formation of the coordination bond between ammonia and Li + in LiNH 2 BH 3 plays a crucial role in promoting the combination of hydridic BH bonds and protic NH bonds, leading to dehydrogenation at low temperature." @default.
• W2005066543 created "2016-06-24" @default.
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• W2005066543 date "2010-03-16" @default.
• W2005066543 modified "2023-10-18" @default.
• W2005066543 title "Amminelithium Amidoborane Li(NH₃)NH₂BH₃: A New Coordination Compound with Favorable Dehydrogenation Characteristics" @default.
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• W2005066543 doi "https://doi.org/10.1002/chem.200903220" @default.
• W2005066543 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20157906" @default.
• W2005066543 hasPublicationYear "2010" @default.
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