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- W2005072879 abstract "Isonicotinic amide was studied by dc and DP polarography and linear sweep cyclic voltammetry in the pH range 3–13. Tafel slopes and reaction orders were obtained at potentials corresponding to the foot of the polarographic wave. Polarographic, voltammetric and kinetic data show that the process consists essentially of two reversible one-electron transfers followed by a protonation reaction, which is the rate-determining step (rds). The proton donors present in the solution, including the H+ ion, are involved in this reaction. In the pH range 6–9, the simultaneous occurrence of two processes taking place at close reduction potentials causes a characteristic variation in the limiting current. At pH > 11 the main protonating species taking part in the rds is the H2O molecule." @default.
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- W2005072879 date "1989-08-01" @default.
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- W2005072879 title "Study of the reduction mechanism of isonicotinamide on mercury electrodes" @default.
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- W2005072879 doi "https://doi.org/10.1016/0022-0728(89)80250-5" @default.
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