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• W2005080267 abstract "N,N′-Dibenzyl-6-hydroxymethyl-6-nitroperhydro-1,4-diazepine was converted into a nitronate via retro-Henry reaction, followed by either Michael reaction with several acrylic derivatives or Mannich reaction with different amines, thus leading to 6-substituted 6-nitroperhydro-1,4-diazepines. The tandem retro-Henry/Mannich reaction was also carried out using benzylamine as base, solvent, and reagent at the same time. Selective hydrogenation of the nitro group and complete hydrogenolysis were also successfully achieved." @default.
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• W2005080267 date "2012-01-19" @default.
• W2005080267 modified "2023-09-24" @default.
• W2005080267 title "Synthesis of 6-Substituted 6-Nitroperhydro-1,4-diazepines via Novel <i>Tandem</i> Retro-Henry and Mannich/Michael Reactions" @default.
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• W2005080267 doi "https://doi.org/10.1021/ol203101s" @default.
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