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- W2005082232 abstract "The standard free energy of formation for zirconium molybdate (ZrMo2O8) was derived from its vapour pressure measured in the temperature range 1029 to 1142 K employing the transpiration technique. ZrMo2O8 vaporizes incongruently according to the reaction n〈ZrMo2O8〉 → n〈ZrO2〉 + 2(MoO3)n, n = 3,4,5. The standard free energy of formation of ZrMo2O8 calculated from the partial pressure of (MoO3)3 in the vapour above ZrMo2O8 + ZrO2 mixture could be expressed by the relation ΔfG°〈ZrMo2O8〉 =(−2525.5±4.9) +(0.6115±0.0045)Tkj/mol (1029) < T/K < 1142). The values of ΔfG°〈ZrMo2O8〉 obtained in this work agree very well with those reported recently from solid electrolyte galvanic cell measurements." @default.
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- W2005082232 date "1993-04-01" @default.
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- W2005082232 title "The standard free energy of formation of ZrMo2O8 by the transpiration method" @default.
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