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• W2005087153 abstract "Micellization of several surfactants in water−organic solvent mixtures has been investigated. Only solvents localized mainly in the bulk phase of the micellar solutions (they do not incorporate into the micelles) were studied, with either higher or lower permittivity than that of pure water. Results show that the influence of organic solvent addition on the aggregation process can be approximately accounted for by considering the changes in the bulk phase cohesive energy density, described by the Gordon parameter, G. To our knowledge, this is the first time that, for a given surfactant, the Gibbs energies of micellization, ΔGM°, obtained in several water−organic solvent mixtures have been fitted together. It is worth noting that data from different research groups have been considered. The ΔGM° versus G correlation will permit the estimation of the variations in the Gibbs energy of micellization upon addition of known quantities of a given polar organic solvent. Speaking in a general way, organic solvent addition results in the bulk phase becoming a better solvent for the surfactant molecules. This would make the hydrophobic tail transfer from the bulk phase into the micelles less favorable and, as a consequence, ΔGM° increases (becomes less negative), making the aggregation process less spontaneous." @default.
• W2005087153 created "2016-06-24" @default.
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• W2005087153 creator A5014748169 @default.
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• W2005087153 date "2008-10-21" @default.
• W2005087153 modified "2023-10-10" @default.
• W2005087153 title "Effects of Addition of Polar Organic Solvents on Micellization" @default.
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• W2005087153 doi "https://doi.org/10.1021/la802320s" @default.
• W2005087153 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18937432" @default.
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