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- W2005087278 abstract "Complexes of the type cis-[Pd(RNC)LCl2] (R = Ph, p-MeC6H4, p-MeOC6H4, p-O2NC6H4; L = PhNC, p-MeC6H4NC, PPh3) react with bifunctional amines, YNH2, such as ethylenediamine, o-phenylenediamine, ethanolamine, 2-aminopyridine and allylamine, to give the neutral carbene derivatives cis-[Pd{C(NHR)NHY}LCl2], in which the functional group Y is not coordinated to the central metal. The coordination of Y can be achieved only by a further reaction with NaClO4 and/or AgBF4. Bis(carbene) derivatives of the type cis-[Pd{C(NHR)NHY}2 Cl2] (R = Ph, p-MeC6H4; YNH2 = 2-aminopyridine) are also reported; they undergo chelation on treatment with NaClO4 and deprotonation on treatment with KOH." @default.
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- W2005087278 date "1974-05-01" @default.
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- W2005087278 title "Reactions of palladium(II) isocyanide complexes with bifunctional amines" @default.
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- W2005087278 doi "https://doi.org/10.1016/s0022-328x(00)93148-6" @default.
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