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- W2005096199 abstract "Abstract The cathodic reduction of oxygen in 1 mol dm −3 sodium hydroxide solutions has been investigated at several types of titanium oxide cathodes. Layers of TiO 2 were prepared on titanium by spraying and thermal decomposition of solutions of titanium n -butoxide in 2-propanol and titanium tetrachloride in methanol+water and also by anodization; the reduction was also studied at Ebonex®, a conducting ceramic consisting mainly of Ti 5 O 9 . In all cases, the reduction of oxygen occurs largely by a 4e − reaction to water and the reaction occurs at potentials close to −1.0 V vs. SCE. Cyclic voltammetry in the absence of oxygen shows that, at these potentials, the surfaces undergo reduction and the electrochemistry of the Fe(CN) 6 4− /Fe(CN) 6 3− couple has been used to probe further the properties of the TiO 2 surfaces." @default.
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- W2005096199 date "1992-11-01" @default.
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- W2005096199 title "The reduction of oxygen on titanium oxide electrodes" @default.
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- W2005096199 doi "https://doi.org/10.1016/0022-0728(92)80303-l" @default.
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