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- W2005099103 abstract "The effect of 15 metal cations and NH+4 on the response current of an inactive polypyrrole uricase electrode has been investigated. Uricase is activated only by Mn2+ among the investigated cations. The response current of the uricase electrode increases with increasing the concentrations of Mn2+ and uric acid. Based on the experimental fact, a mechanism of the activation kinetics of immobilized uricase in the presence of Mn2+ is presented, that is, E + M ⇌ EM, EM + S ⇌ EMS → EM + P, and a rate equation from this model is given. The activation time of the immobilized uricase relates to an applied potential and less than 10s at potentials above 0.375 V." @default.
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- W2005099103 date "1994-01-01" @default.
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- W2005099103 title "The kinetics of activated uricase immobilized on a polypyrrole film" @default.
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- W2005099103 doi "https://doi.org/10.1016/0013-4686(94)85004-6" @default.
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