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- W2005103601 abstract "A phase transformation in EU3S4 at 168°K has been established by several different experimental methods. Electrical conductivity and Seebeck coefficient measurements show a discontinuity through the transition. Above the transition temperature, the activation energy for conduction is 0.163 eV and the resistivity is about 3 × 104Ωcm, while below the transition the activation energy is 0.21 eV and the resistivity is about 106 Ωcm. Differential thermal analysis thermograms reveal an endothermic peak on heating with a hysteresis of 5°C. X-ray diffraction experiments show a change in symmetry accompanied by a lattice parameter change of approximately 0.4% for the transition. Measurements of the magnetic susceptibility show the transition not to be magnetic in origin. It is proposed that the transformation in EU3S4 is due to charge ordering which produces tetragonal symmetry in the unit cell." @default.
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- W2005103601 title "Observation of a phase transformation in Eu3S4 at 168°K" @default.
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- W2005103601 doi "https://doi.org/10.1016/0022-5088(70)90019-6" @default.
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