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- W2005103935 abstract "The V(III)/V(II) system has been investigated polarographically in HClO4 + NaClO4 aqueous solutions of pH ranging from 0 to 4.6 at constant ionic strength equal to 1 mol dm−3. Low concentration of vanadium ions, 0.47 mM, was used in order to avoid their polynuclear hydrolysis. While an oxidation wave of V(II) was practically-pH independent, large pH effects on a reduction wave of V(III) were found: (i) a shift toward more negative potentials; (ii) a split into several compositional waves; (iii) gradual decrease of the total wave with a rise in pH.These pH effects have been ascribed to the formation of reducible, mononuclear V(III) hydroxycomplexes such as VOH2+, V(OH)2+ and V(OH)3 as well as to a precipitation of V(III) hydroxide. Very slow equilibration of V(III) solutions hydrolysed above a pH ⋍ 3.8 has been found." @default.
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- W2005103935 title "Hydrolysis of vanadium ions (III, II) and polarographic behaviour of the V(III)/V(II) system in aqueous perchlorate solutions" @default.
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- W2005103935 doi "https://doi.org/10.1016/0013-4686(89)87059-8" @default.
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