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• W2005116879 abstract "Nano-sized CSO (Ce0.80Sm0.20O2−δ) and CSCO (Ce0.79Sm0.20Cu0.01O2−δ) were synthesized by the PVA assisted combustion method, and then characterized by the structure of PVA–cation complexes and nano-powders, as well as mechanical and electrical performance after sintering. The results indicate that the PVA–cation complexes (PVA–(Ce3+,Sm3+) and PVA–(Ce3+,Sm3+,Cu2+)) were formed by coordinating metal cations to hydroxyl groups, as well as the COO−1 group derived from the oxidation of PVA with NO3−1. Low temperatures (around 200 °C) caused intense combustion reactions, resulting in the direct crystallization of cubic fluorite nano-CSO (10–20 nm) and nano-CSCO (10–15 nm) crystals with homogeneous element distribution. This slight compositional modification of CSO by co-doping with 1 mol% CuO resulted in a significantly lowered densification temperature, as well as enhanced mechanical and electrical property. The strength improvement can be ascribed to the dense and fine-grained microstructure without normal grain coarsening, resulting in a transgranular-dominant fracture mode during strength testing." @default.
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• W2005116879 date "2011-11-01" @default.
• W2005116879 modified "2023-10-18" @default.
• W2005116879 title "Combustion synthesis and characterization of Cu–Sm co-doped CeO2 electrolytes" @default.
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• W2005116879 doi "https://doi.org/10.1016/j.jeurceramsoc.2011.04.037" @default.
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