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- W2005117448 abstract "Abstract A microcanonical version of the transition state theory, TST, combined with the statistical adiabatic channel model, SACM, show the importance of quantum effects induced by the changes in angular momentum in the ion-dipole captures that occur at low energies. At extremely low energies the coupling of orbital and rotational motion becomes the rate determining factor. Hence, the theories based on the Born-Oppenheimer approximation are completely inadequate at such energies. The correct rate parameters that account both for the quantization of angular momentum and the coupling of orbital-rotational motions are reported for some model systems." @default.
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- W2005117448 title "Quantum effects in the ion-dipole capture" @default.
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- W2005117448 doi "https://doi.org/10.1016/0301-0104(90)90027-7" @default.
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