Matches in SemOpenAlex for { <https://semopenalex.org/work/W2005143485> ?p ?o ?g. }
- W2005143485 abstract "Abstract A vibronic analysis of the fluorescence spectrum of styrene in crystalline solution at 77 K corroborates the assignment of the O.O band at 34758 cm −1 for gas-phase spectra. The torsional frequency of the vinyl group with respect to the phenyl ring is used to evaluate the internal rotation barrier of styrene (5.7 kcal mol −1 ). Configuration interaction MO calculations including all the mono and di-excilations within the π-electron system of styrene suggest that the first π—π * transition has a moment tilted by 10° with respect to the long axis of the molecule; this is in agreement with the rotational structure of the gas-phase band at 34758 cm −1 , the analysis of which results in an A-type band." @default.
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- W2005143485 date "1977-05-01" @default.
- W2005143485 modified "2023-10-02" @default.
- W2005143485 title "Fluorescence à 77 K, rotation interne et structure electronique du styréne" @default.
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- W2005143485 doi "https://doi.org/10.1016/0022-2860(77)87084-1" @default.
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