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- W2005144334 abstract "Free radical copolymerization of maleic anhydride (M1) with cyclohexene (M2) was carried out with 2,2′‐azobis(isobutyronitrile) as an initiator in various solvents. The copolymerization of maleic anhydride with cyclohexene in benzene and toluene proceeded in a heterogeneous system to give an alternating copolymer independent of the monomer composition in the feed. The powerful alternation tendency cannot be explained by the participation of charge‐transfer complex in the propagation due to the absence of charge‐transfer complex formation between maleic anhydride and cyclohexene in the copolymerization system. Furthermore, the initial rate of copolymerization (Rp) was found depend on the monomer composition and was a maximum of about 60 mol% of maleic anhydride in the feed. A solvent effect on the copolymerization system was also investigated, i. e., copolymerization in benzene produced a higher Rp than that in toluene or in chloroform. The copolymer was characterized by 1H‐NMR and 13C‐NMR spectra." @default.
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- W2005144334 date "2005-04-13" @default.
- W2005144334 modified "2023-09-26" @default.
- W2005144334 title "Free Radical Copolymerization of Maleic Anhydride with Cyclohexene" @default.
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- W2005144334 doi "https://doi.org/10.1081/ma-200054341" @default.
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