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- W2005149005 abstract "Rhodium siloxide immobilized on silica support was prepared and used for hydrosilylation of alkenes as a recyclable catalyst. Thus, [Rh(µ-OSiMe3)(cod)]2 reacted with aerosil silica (Aerosil 200) in hexane or benzene at r.t. for 24 h to give the rhodium siloxide immobilized on silica support. Hydrosilylation of alkenes with heptamethylhydrotrisiloxane was carried out with the heterogeneous Rh siloxide catalyst (0.01 mol% Rh) to afford the corresponding hydrosilylation products in 88-97% yield (4 examples; TOF = 147-162/min). The catalyst was reused 15-20 times without significant loss of catalytic activity." @default.
- W2005149005 created "2016-06-24" @default.
- W2005149005 date "2008-02-21" @default.
- W2005149005 modified "2023-09-26" @default.
- W2005149005 title "Silica-Supported Rhodium Catalyst for Hydrosilylation of Alkenes" @default.
- W2005149005 doi "https://doi.org/10.1055/s-2008-1042667" @default.
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