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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2005150426> ?p ?o ?g. }

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• W2005150426 abstract "A method using nitroxide radical spin labels for determining both the isotropic rotational correlation time τR and the environmental polarity of the label is described. By means of a least square fitting method, the values of an effective hyperfine tensor A′ and of an effective g value tensor g′ of randomly oriented spin labels are determined from X-band EPR spectra on the basis of an effective time-independent Hamiltonian. The traces of the tensors deliver the information about the environmental polarity of the label and are not dependent on the rotational correlation time τR. A new averaging parameter S (τR), calculated on the basis of the principal values of the tensor A′, permits the evaluation of the rotational correlation time τR in a very wide time range between 10−10 and 10−6 s. An application of this method to spin-labeled methemoglobin over a large temperature range and in environments of different polarity is discussed." @default.
• W2005150426 created "2016-06-24" @default.
• W2005150426 creator A5006843776 @default.
• W2005150426 date "1988-12-01" @default.
• W2005150426 modified "2023-10-18" @default.
• W2005150426 title "A simple method for determination of rotational correlation times and separation of rotational and polarity effects from EPR spectra of spin-labeled biomolecules in a wide correlation time range" @default.
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• W2005150426 doi "https://doi.org/10.1016/0165-022x(88)90047-4" @default.
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