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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2005169281> ?p ?o ?g. }

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• W2005169281 abstract "Allyl alcohols were converted to allyl boronic acids and subsequently to trifluoro(allyl)borates with tetrahydroxy diboron using palladium pincer-complex catalysis. These reactions are regio- and stereoselective proceeding with high isolated yields. Competitive boronation experiments indicate that under the applied reaction conditions the allylic displacement of a hydroxy group is faster than the displacement of an acetate leaving group. It is assumed that the hydroxy group of the allyl alcohol is converted to a diboronic acid ester functionality, which can easily be substituted." @default.
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• W2005169281 date "2006-03-22" @default.
• W2005169281 modified "2023-10-16" @default.
• W2005169281 title "Direct Boronation of Allyl Alcohols with Diboronic Acid Using Palladium Pincer-Complex Catalysis. A Remarkably Facile Allylic Displacement of the Hydroxy Group under Mild Reaction Conditions" @default.
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• W2005169281 doi "https://doi.org/10.1021/ja060468n" @default.
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