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• W2005173822 abstract "La variation de la conductivité électrique en fonction de la composition fait apparaitre une différence importance entres les deux systèmes vitreux AgPO3PbI2 et AgPO3HgI2. Des verres appartenant à ces systèmes, utilisés dans des électrodes spécifiques ioniques en solution aqueuse présentent aussi un comportement différent vis-à-vis de l'ion divalent correspondant. Une interprétation faisant appel à des considérations structurales peut être avancée pour expliquer ces différences. Une étude similaire avec les systèmes AgAsS2MI2 ne permet pas de confirmer cette interprétation en l'absence d'études structurales. The dependence of electrical conductivity with composition shows a different behaviour between the two following glassy systems: AgPO3PbI2 and AgPO3HgI2. Such materials have been used as membranes for ion-selective electrodes in aqueous solutions. They exhibit different responses towards the corresponding divalent ion (eg Pb2+, and Hg2+ respectively). An interpretation based on a structural approach is proposed to explain these behaviours. However, this interpretation cannot be confirmed with AgAsS2MI2 glassy systems without further structural data." @default.
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• W2005173822 date "1981-08-01" @default.
• W2005173822 modified "2023-09-25" @default.
• W2005173822 title "Conductivite electrique et selectivite ionique des verres AgPO3MI2 et AgAsS2MI2 avec M = Pb, Hg" @default.
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• W2005173822 doi "https://doi.org/10.1016/0013-4686(81)85090-6" @default.
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